Preheat oven to 325 degrees F. Prepare three 8 inch or four 6 inch round pans with nonstick spray, parchment paper and another layer of nonstick spray.
Sift together flour, baking powder, salt and cinnamon. Set aside.
Stir vanilla into buttermilk. Set aside.
In the bowl of a stand mixer, beat the butter and sugar on medium-high speed using the paddle attachment. Cream until pale and fluffy, about 5 minutes.
With the mixer on low, add egg whites one at a time. Mixing well after each egg.
Add one third of your dry ingredients and mix just until combined.
Add one half of your buttermilk. Mix. Alternate ingredients again. Dry, wet, dry and mix gently. Do not over mix.
Divide batter evenly between the prepared pans. Bake 35-40 minutes. Cake is finished when a toothpick comes out with a few moist crumbs on it.
Cool 10-20 minutes before inverting cakes from pans. Cool completely before assembling cake or wrap with plastic wrap and refrigerate if not using until the next day.